Title: Are the local communities safe? Assessing the slag management practices in the ferro-chromium smelting industry and the risk of chromium (VI) in the reuse applications in Zimbabwe

Authors: Winmore Kusena; Mitchell Faith Muwairi; Melanie D. Nicolau

Addresses: Midlands State University, P. Bag 9055, Gweru, Zimbabwe; University of South Africa, 28 Pioneer Ave, Florida Park, Roodepoort, 1709, South Africa ' Zimbabwe Alloys Chrome, Number 1899 Bristol Road, Gweru, Zimbabwe ' University of South Africa, 28 Pioneer Ave, Florida Park, Roodepoort, 1709, South Africa

Abstract: Ferro-chromium smelting has contributed to the accumulation of vast amounts of slag in developing countries. The current study examines the slag management measures at Zimbabwe Alloys Chrome (ZAC) and determined possible chromium (VI) leaching into different environments. The research incorporated both the qualitative and quantitative data collection methods. The leading solid waste management practice was disposal to landfill, which is the least preferred option on the solid waste management hierarchy. All the sampled water sources around ZAC showed traces of chromium (VI) above acceptable standards. Chromium six levels also exceeded the environmental management act (EMA) regulations of 0.05 mg/l, the EPA standards of 0.01 mg/l, and OSHA limits of 0.01 mg/l under neutral, alkaline, and acidic laboratory environments. The findings imply a lack of sustainable waste management practices at ZAC that expose communities to chromium (VI). The study highlighted an urgent need for ZAC landfill remediation to protect the water bodies and communities exposed to the slag reuse applications.

Keywords: ferro-chromium; chromium (VI); waste management practices; Zimbabwe alloys chrome; slag; leachability; smelting industries.

DOI: 10.1504/IJEWM.2025.144247

International Journal of Environment and Waste Management, 2025 Vol.36 No.2, pp.227 - 242

Accepted: 01 Jul 2022
Published online: 03 Feb 2025 *

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