Article: Stable dispersions of single-walled carbon nanotubes Journal: International Journal of Environment and Health (IJENVH) 2009 Vol.3 No.3 pp.285 - 301 Abstract: The degree of dispersion of Single-Walled Carbon Nanotubes (SWCNTs) in different solvents is an issue in all studies where applications (in microelectronics, as well as in biological in vitro and in vivo systems) are envisaged. We performed long-term dispersion studies of SWCNTs in four different solvents: phosphate buffer solution (PBS), poly(sodium 4-styrene-sulfonate) (NaPSS), Gum Arabic (GA), and a mixture of dipalmitoylphosphatidylcholine and bovine serum albumin (DPPC/BSA). The dispersion of the composite SWCNT-COOH/polyethylenimine (PEI) in phosphate buffer solution was also investigated. Purification pre-treatments were performed on the samples and checks were made prior to the dispersion studies, to make sure that the chemical treatments did not introduce new functionalities. Similarly, preliminary control studies were performed with SWCNT-COOH/PEI to ensure that the synthesis procedure was correct. We found that GA and DPPC/BSA were the best solvents for the dispersion of the SWCNTs, with the stability of the homogenous solution longer than one month. The dispersion of SWCNT-COOH/PEI in PBS is stable for over six months. Inderscience Publishers - linking academia, business and industry through research

Title: Stable dispersions of single-walled carbon nanotubes

Authors: Federica Valentini, Marta Amadei, Giuseppe Palleschi, Marilena Carbone

Addresses: Universita degli Studi di Roma Tor Vergata, Dipartimento di Scienze e Tecnologie Chimiche, via della Ricerca Scientifica 1, 00133 Roma, Italy. ' Universita degli Studi di Roma Tor Vergata, Dipartimento di Scienze e Tecnologie Chimiche, via della Ricerca Scientifica 1, 00133 Roma, Italy. ' Universita degli Studi di Roma Tor Vergata, Dipartimento di Scienze e Tecnologie Chimiche, via della Ricerca Scientifica 1, 00133 Roma, Italy. ' Universita degli Studi di Roma Tor Vergata, Dipartimento di Scienze e Tecnologie Chimiche, via della Ricerca Scientifica 1, 00133 Roma, Italy

Abstract: The degree of dispersion of Single-Walled Carbon Nanotubes (SWCNTs) in different solvents is an issue in all studies where applications (in microelectronics, as well as in biological in vitro and in vivo systems) are envisaged. We performed long-term dispersion studies of SWCNTs in four different solvents: phosphate buffer solution (PBS), poly(sodium 4-styrene-sulfonate) (NaPSS), Gum Arabic (GA), and a mixture of dipalmitoylphosphatidylcholine and bovine serum albumin (DPPC/BSA). The dispersion of the composite SWCNT-COOH/polyethylenimine (PEI) in phosphate buffer solution was also investigated. Purification pre-treatments were performed on the samples and checks were made prior to the dispersion studies, to make sure that the chemical treatments did not introduce new functionalities. Similarly, preliminary control studies were performed with SWCNT-COOH/PEI to ensure that the synthesis procedure was correct. We found that GA and DPPC/BSA were the best solvents for the dispersion of the SWCNTs, with the stability of the homogenous solution longer than one month. The dispersion of SWCNT-COOH/PEI in PBS is stable for over six months.

Keywords: single-walled carbon nanotubes; CNT; stable dispersion; nanocomposites; functionalisation; purification; environmental health; nanotechnology; solvents.

DOI: 10.1504/IJENVH.2009.028595

International Journal of Environment and Health, 2009 Vol.3 No.3, pp.285 - 301

Published online: 19 Sep 2009 *

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Title: Stable dispersions of single-walled carbon nanotubes

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