Effect of annealing on the structural and optical properties of sputtered HfNx thin films
by H. Gueddaoui; G. Schmerber
International Journal of Nanoparticles (IJNP), Vol. 6, No. 2/3, 2013

Abstract: HfNx films deposited by dc reactive magnetron sputtering at 150°C were annealed for 60 minutes at 400°C under a continuous 4.5 sccm argon gas flow. The X-ray diffraction (XRD) analysis of annealed films showed the existence of hexagonal (hcp-HfNx) and rock-salt (fcc-HfNx) phases in the chemical composition range 0.34 ≤ × ≤ 1.25. By using the Drude-Lorentz model, good agreement was found between experimental and calculated reflectance spectra in the energy range extending from 0.5 to 6.5 eV. The annealing treatment has two main effects: the first to increase the damping factor of the conduction of free carriers for x > 1.19 with a significant change in the plasma frequency, and the second to shift the screened plasma frequency towards lower energies.

Online publication date: Mon, 31-Mar-2014

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